| 張永明 |
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張永明，男，1960年出生，1999年畢業于華東理工大學，獲材料科學與工程專業博士學位，同年進入上海交通大學工作，現為上海交通大學教授，上海市領軍人才，全國勞動模范，享受國務院政府特殊津貼專家，“泰山學者”特聘專家。從事含氟聚合物和含氟功能膜的研發。主持并圓滿完成國家863計劃、支撐計劃重大項目，實現了氯堿工業全氟離子膜的產業化，結束了中國沒有全氟離子膜的歷史，打破了制約我國氯堿工業安全運行和健康發展的瓶頸，是中國氯堿工業發展的里程碑。同時開展的研究包括燃料電池新能源汽車核心材料、催化分離膜材料、海水淡化膜材料、儲能電池膜材料、特種潤滑材料等。所著《含氟功能材料》被評為化工領域科技圖書一等獎。
主要研究方向
特種功能高分子材料
新能源汽車核心材料
催化分離膜材料、儲能電池膜材料
光電功能材料與生物材料
主持項目
歐盟第七框架項目
“十五”863計劃重大課題“全氟離子交換膜材料關鍵技術研究”
“十一五”國家支撐計劃重大項目“全氟離子膜工程技術研究”
“十一五”863計劃重點項目“新型制氫及高溫質子交換膜燃料電池技術研發與應用示范”
“十二五”國家支撐計劃重點項目“氯堿離子膜大規模應用研究”
歐盟第六框架項目
中加合作項目“新型燃料電池質子膜研究”
獲獎情況
2007年山東省“泰山學者”
2009年山東省技術發明一等獎（排名第一）
2010全國勞動模范
2010年享受國務院特殊津貼專家
2010年所著《含氟功能材料》獲中國石化工業優秀出版物獎（圖書獎）一等獎（排名第一）
2010年“全氟離子交換膜工程技術研究”入選“十一五”國家重大科技成就
2011年“全氟離子膜工程技術研究團隊”獲“十一五”國家科技計劃執行優秀團隊獎
2011年獲中國石化聯合會科技進步二等獎（排名第一）
2011年獲國家技術發明二等獎（排名第一）
2012年獲“何梁何利科學與技術進步獎”
2012年獲“上海市領軍人才”稱號
2013年上海交通大學“凱原十佳教師”
主要學術兼職
國家分離膜標準化技術委員會委員
科技部國際合作評審專家
中國科技獎勵評審專家
中國膜工業協會專家
中國氯堿協會專家
中國氟硅協會專家
中國無機鹽協會專家
中國儀表功能膜材料協會專家
《膜科學與技術》編委
《氯堿工業》編委
Publication List
2013
69 Yuan, W. Z.; Tan, Y.; Gong, Y.; Lu, P.; Lam, J. W. Y.; Shen, X. Y.; Feng, C.; Sung, H. H-Y.; Lu, Y.; Williams, I. D.; Sun, J. Z.; Zhang, Y.; Tang, B. Z. “Synergy between Twisted Conformation and Effective Intermolecular Interactions: Strategy for Efficient Mechanochromic Luminogens with High Contrast” Advanced Materials 2013, 26, 2837.
68 Gong, Y.; Tan, Y.; Liu, J.; Lu, P.; Feng, C.; Yuan, W. Z.; Lu, Y.; Sun, J. Z.; He, G.; Zhang, Y. “Twisted D–pi–A solid emitters: efficient emission and high contrast mechanochromism” Chemical Communications 2013, 49, 4009.
67 Zhu, Y.; Pei, S.; Tang, J.; Li, H.; Wang, L.; Yuan, W. Z.; Zhang, Y. “Enhanced chemical durability of perfluorosulfonic acid membranes through incorporation of terephthalic acid as radical scavenger” Journal of Membrane Science 2013, 432,
66 Yang, L.; Tang, J.; Li, L.; Ai, F.; Chen, X.; Yuan, W. Z.; Zhang, Y. “Properties of precursor solution cast PFSI membranes with various ion exchange capacities and annealing temperatures” RSC Advances 2013, 3, 7289.
65 Tang, J.; Yuan, W.; Zhang, Z.; Li, H.; Zhang, Y. “Evidence for a crystallite-rich skin on perfluorosulfonate ionomer membranes” RSC Advances 2013, 3, 8947.
64 Wang, C.; Li, H.; Zhao, J.; Zhu, Y.; Yuan, W. Z.; Zhang, Y. “Graphene Nanoribbons as A Novel Support Material for High Performance Fuel Cell Electrocatalysts” International Journal of Hydrogen Energy 2013, 38, 13230.
63 Yang, L.; Li, H.; Ai, F.; Chen, X.; Tang, J.; Zhu, Y.; Wang, C.; Yuan, W. Z.; Zhang, Y. “A New Method to Prepare High Performance Perfluorinated Sulfonicacid Ionomer/Porous Expanded Polytetrafluoroethylene Composite Membranes Based on Perfluorinated Sulfonyl Fluoride Polymer Solution” Journal of Power Sources 2013, 243, 392.
62 Gong, YY.; Tan, YQ.; Mei, J.; Zhang, YR.; Yuan, WZ.; Zhang, YM.; Sun, JZ.; Tang, B. Z. “Room temperature phosphorescence from natural products: Crystallization matters” Science China Chemistry 2013, 56, 1178.
61 Gong, YY.; Tan, YQ.; Li, H.; Zhang, YR.; Yuan, WZ.; Zhang, YM.; Sun, JZ.; Tang, B. Z. “Crystallization-induced phosphorescence of benzils at room temperature” Science China Chemistry 2013, 56, 1183.
60 Lu, YW.; Tan, YQ.; Gong, YY.; Li, H.; Yuan, WZ.; Zhang, YM.; Tang, B. Z. “High efficiency D-A structured luminogen with aggregation-induced emission and mechanochromic characteristics” Chinese Science Bulletin 2013, 58, 2719.
2012
59 Tang, J.; Yuan, W.; Wang, J.; Tang, J.; Li, H.; Zhang, Y. “Perfluorosulfonate ionomer membranes with improved through-plane proton conductivity fabricated under magnetic field” Journal of Membrane Science 2012, 423–424, 267.
58 Cai, Z.; Li, L.; Su, L.; Zhang, Y. “Supercritical carbon dioxide treated Nafion 212 commercial membranes for direct methanol fuel cells” Electrochemistry Communications 2012, 14, 9.
57 Cai, Z.; Liu, Y.; Zhao, J.; Li, L.; Zhang, Y.; Zhang, J. “Tris(trimethylsilyl) borate as electrolyte additive to improve performance of lithium-ion batteries” Journal of Power Sources 2012, 202, 341.
56 Yang, L.; Yuan, W.; Zhao, J.; Ai, F.; Chen, X.; Zhang, Y. “A Novel Approach to Prepare Uniaxially Aligned Nanofibers and Longitudinally Aligned Seamless Tubes Through Electrospinning” Macromolecular Materials and Engineering 2012, 297, 604.
55 Li, L.; Su, L.; Zhang, Y. “Enhanced performance of supercritical CO2 treated Nafion 212 membranes for direct methanol fuel cells” International Journal of Hydrogen Energy 2012, 37, 4439.
54 Cai, Z.; Liu, Y.; Liu, S.; Li, L.; Zhang, Y. “High performance of lithium-ion polymer battery based on non-aqueous lithiated perfluorinated sulfonic ion-exchange membranes” Energy & Environmental Science 2012, 5, 5690.
53 Chen, X.; Yuan, W. Z.; Zhao, J.; Yang, L.; Li, H.; Li, L.; Zhang, Y. “Thermal-mechanical stability of ethylene tetrafluoroethylene alternating copolymer, and modification thereof” Journal of Polymer Research 2012, 19, 9820.
52 Xu, A.; Yuan, W. Z.; Zhang, H.; Wang, L.; Li, H.; Zhang, Y. “Low-molecular-weight polytetrafluoroethylene bearing thermally stable perfluoroalkyl end-groups prepared in supercritical carbon dioxide” Polymer International 2012, 61 , 901.
51 Chen, X.; Yuan, W. Z.; Li, H.; Zhang, Y. “Rheological study on tetrafluoroethylene/hexafluoropropylene copolymer and its implication for processability” Journal of Applied Polymer Science 2012, 125, 3361.
50 Qin, S.; Li, H.; Yuan, W. Z.; Zhang, Y. “Fluorine-containing block copolymer particles with surface and internal hierarchical microphase separation structures” Soft Matter 2012, 8, 2471.
49 Qin, S.; Yuan, W. Z.; Li, H.; Zhang, Y. “Order–order phase transition and transformation in co-assembled particles from fluorinated FA/FB type diblock copolymers” Soft Matter 2012, 8, 8405.
48 Xu, A.; Li, H.; Yuan, W. Z.; Geng, B.; Zhang, S.; Zhang, H.; Wang, L.; Zhang, Y. “Radical homopolymerization of tetrafluoroethylene initiated by perfluorodiacyl peroxide in supercritical carbon dioxide: Reaction mechanism and initiation kinetics” European Polymer Journal 2012, 48,1431.
47 Yang, L.; Tang, J.; Li, L.; Chen, X.; Ai, F.; Yuan, W. Z.; Wang, L.; Zhang, Y. “High quality pristine perfluorosulfonated ionomer membranes prepared from perfluorinated sulfonyl fluoride solution” RSC Advances 2012, 2, 5950.
46 Chen, X.Y.; Yuan, W. Z.; Ai, F.; Li, H.; Li, L.; Wang, J.; Zhang, Y. “Melt rheological properties of ETFE: an attempt to illuminate the fluorine-substitution effect” Polymer Bulletin 2012, 69, 375.
45 Ai, F.; Wang, Q.; Yuan, W. Z.; Li, H.; Chen, X.; Yang, L.; Zhang, Y.; Pei, S. “Biocompatibility and anti-cracking performance of perfluorocarboxylic acid ionomer membranes for implantable biosensors” Journal of Materials Science 2012, 47, 5181.
44 Xu, A.; Yuan, W. Z.; Zhao, J.; Li, H.; Zhang, H.; Zhang, Y. “Copolymerizations of tetrafluoroethylene and perfluoropropylvinyl ether in supercritical carbon dioxide: Polymer synthesis, characterization, and thermal properties” Journal of Applied Polymer Science 2012, 124, 1785.
43 Zhu, H.; Tong, H.; Gong, Y.; Shao, S.; Deng, C.; Yuan, W. Z.; Zhang, Y. “Fluorene-and benzimidazole-based blue light-emitting copolymers: Synthesis, photophysical properties, and PLED applications” Journal of Polymer Science Part A: Polymer Chemistry 2012, 50 , 2172.
42 Qin, S.; Li, H.; Yuan, W. Z.; Zhang, Y. “Fabrication of polymeric honeycomb microporous films: breath figures strategy and stabilization of water droplets by fluorinated diblock copolymer micelles” Journal of Materials Science 2012, 47, 6862.
41 Ai, F.; Li, H.; Wang, Q.; Yuan, W. Z.; Chen, X.; Yang, L.; Zhao, J.; Zhang, Y. “Surface characteristics and blood compatibility of PVDF/PMMA membranes” Journal of Materials Science 2012, 47, 5030.
40 Chen, X. Y.; Zhang, Y. M. “Determining molecular weight scale and molecular weight distribution of ethylene-tetrafluoroethylene alternating copolymer via a rheological technique” Journal of Applied Polymer Science 2012, 125, 2442.
39 Yuan, W. Z.; Gong, Y.; Chen, S.; Shen, X. Y.; Lam, J. W.; Lu, P.; Lu, Y.; Wang, Z.; Hu, R.; Xie, N. “Efficient Solid Emitters with Aggregation-Induced Emission and Intramolecular Charge Transfer Characteristics: Molecular Design, Synthesis, Photophysical Behaviors, and OLED Application” Chemistry of Materials 2012, 24, 1518.
38 Yang, C.; Castelvetro, V.; Zhang, Y.; Hu, C. “Facile hydrophobic modification of hybrid poly (urethane-urea) methacrylate aqueous dispersions and films through blending with novel waterborne fluorinated acrylic copolymers” Colloid and Polymer Science 2012, 290, 491.
37 Ai, F.; Yuan, W. Z.; Wang, Q.; Li, H.; Zhang, Y.; Pei, S. “Enhancing the anti-cracking performance of perfluorosulfonic acid membranes for implantable biosensors through supercritical CO2 treatment” Journal of Materials Science 2012, 47, 3602.
2011
36 Zhao, J.; Xu, A.; Yuan, W. Z.; Gao, J.; Tang, J.; Wang, L.; Ai, F.; Zhang, Y. “Evaluation of electrospun nanofiber formation of perfluorosulfonic acid and poly (N-vinylpyrrolidone) through solution rheology” Journal of Materials Science 2011, 46, 7501.
35 Peron, J.; Edwards, D.; Haldane, M.; Luo, X.; Zhang, Y.; Holdcroft, S.; Shi, Z. “Fuel cell catalyst layers containing short-side-chain perfluorosulfonic acid ionomers” Journal of Power Sources 2011, 196, 179.
34 Yang, C.; Castelvetro, V.; Scalarone, D.; Bianchi, S.; Zhang, Y. “Three different β-cyclodextrins direct the emulsion copolymerization of a highly fluorinated methacrylate toward distinctive nanostructured particle morphologies’’ Journal of Polymer Science Part A: Polymer Chemistry 2011, 49, 4518.
33 Zhao, J.; Yuan, W. Z.; Xu, A.; Ai, F.; Lu, Y.; Zhang, Y. “Perfluorinated sulfonic acid ionomer/poly (N-vinylpyrrolidone) nanofiber membranes: Electrospinning fabrication, water stability, and metal ion removal applications” Reactive and Functional Polymers 2011, 71, 1102.
32 Luo, X.; Holdcroft, S.; Mani, A.; Zhang, Y.; Shi, Z. “Water, proton, and oxygen transport in high IEC, short side chain PFSA ionomer membranes: consequences of a frustrated network” Physical Chemistry Chemical Physics 2011, 13, 18055.
31 Xu, A.; Zhao, J.; Yuan, W. Z.; Li, H.; Zhang, H.; Wang, L.; Zhang, Y. “Tetrafluoroethylene Copolymers with Sulfonyl Fluoride Pendants: Syntheses in Supercritical Carbon Dioxide, Polymerization Behaviors, and Properties” Macromolecular Chemistry and Physics 2011, 212, 1497.
30 Qin, S.; Li, H.; Yuan, W.; Zhang, Y. “Hierarchical self-assembly of fluorine-containing diblock copolymer: From onion-like nanospheres to superstructured microspheres” Polymer 2011, 52, 1191.
29 Yuan, W. Z.; Chen, S.; Lam, J. W.; Deng, C.; Lu, P.; Sung, H. H.; Williams, I. D.; Kwok, H. S.; Zhang, Y.; Tang, B. Z. “Towards high efficiency solid emitters with aggregation-induced emission and electron-transport characteristics” Chemical Communications 2011, 47, 11216.
2010
28 Li, L.; Shang, F.; Wang, L.; Pei, S.; Zhang, Y. “Transport properties of PFSA membranes with various ion exchange capacities for direct methanol fuel cell application” Energy & Environmental Science 2010, 3, 114.
27 Wen, X. W.; Pei, S. P.; Li, H.; Ai, F.; Chen, H.; Li, K. Y.; Wang, Q.; Zhang, Y. M. “Study on an antifouling and blood compatible poly (ethylene–vinyl acetate) material with fluorinated surface structure” Journal of Materials Science 2010, 45, 2788.
26 Pei, S.; Qu, S.; Zhang, Y. “Direct Electrochemistry and Electrocatalysis of Hemoglobin at Mesoporous Carbon Modified Electrode” Sensors 2010, 10, 1279.
2009
25 Zhao, H.; Yang, J.; Li, L.; Li, H.; Wang, J.; Zhang, Y. “Effect of over-oxidation treatment of Pt–Co/polypyrrole-carbon nanotube catalysts on methanol oxidation” International Journal of Hydrogen Energy 2009, 34, 3908.
24 Su, L.; Li, L.; Li, H.; Zhang, Y.; Yu, W.; Zhou, C. “Perfluorosulfonic acid membranes treated by supercritical carbon dioxide method for direct methanol fuel cell application” Journal of Membrane Science 2009, 335, 118.
23 Li, W.; Li, H.; Zhang, Y. M. “Preparation and investigation of PVDF/PMMA/TiO2 composite film” Journal of Materials Science 2009, 44, 2977.
22 Su, L.; Li, L.; Li, H.; Tang, J.; Zhang, Y.; Yu, W.; Zhou, C. “Preparation of polysiloxane modified perfluorosulfonic acid composite membranes assisted by supercritical carbon dioxide for direct methanol fuel cell” Journal of Power Sources 2009, 194, 220.
21 Su, L.; Pei, S.; Li, L.; Li, H.; Zhang, Y.; Yu, W.; Zhou, C. “Preparation of polysiloxane/perfluorosulfonic acid nanocomposite membranes in supercritical carbon dioxide system for direct methanol fuel cell” International Journal of Hydrogen Energy 2009, 34, 6892.
20 Shang, F.; Li, L.; Zhang, Y.; Li, H. “PWA/silica/PFSA composite membrane for direct methanol fuel cells” Journal of Materials Science 2009, 44, 4383.
19 Chen, H.; Li, H.; Pei, S.; Wen, X.; Zhang, Y. “Synthesis and characterization of fluoropoly (amide–sulfonamide) s via polycondensation” Polymer 2009, 50, 4317.
18 Chen, H.; Huang, Z.; Li, H.; Zhang, Y.; Liu, Y. “Synthesis of pure (Co) polymers via supported cobalt (II)-catalyzed controlled/“living” radical polymerization” Polymer Bulletin 2009, 62, 151.
17 Han, L.; Zhang, Y.; Li, H.; Li, L. “The synthesis and surface activity of perfluoro-2, 5-dimethyl-3,6-dioxanonanoic acid ester fluorocarbon surfactants’’ Colloids and Surfaces A: Physicochemical and Engineering Aspects 2009, 334, 176.
2008
16 Luan, Y.; Zhang, Y.; Zhang, H.; Li, L.; Li, H.; Liu, Y. “Annealing effect of perfluorosulfonated ionomer membranes on proton conductivity and methanol permeability” Journal of Applied Polymer Science 2008, 107, 396.
15 Huang, Z. X.; Zhang, Y. M.; Li, H.; Liu, Y. G. “Controlled/“living” radical polymerization of methyl methacrylate catalyzed by cobalt acetate” Macromolecular Chemistry and Physics 2008, 209, 825.
14 Luan, Y.; Zhang, H.; Zhang, Y.; Li, L.; Li, H.; Liu, Y. “Study on structural evolution of perfluorosulfonic ionomer from concentrated DMF-based solution to membranes” Journal of Membrane Science 2008, 319, 91.
13 Huang, Z. X.; Zhang, Y. M.; Li, H.; Luan, Y. H.; Liu, Y. G. “Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co (II) hybrid catalyst” Journal of Polymer Science Part A: Polymer Chemistry 2008, 46 , 1416.
12 Li, L.; Zhang, Y. “Chemical modification of Nafion membrane with 3,4-ethylenedioxythiophene for direct methanol fuel cell application” Journal of Power Sources 2008, 175, 256.
11 Zhao, H.; Li, L.; Yang, J.; Zhang, Y. “Co@ Pt–Ru core-shell nanoparticles supported on multiwalled carbon nanotube for methanol oxidation” Electrochemistry Communications 2008, 10, 1527.
10 Zhao, H.; Li, L.; Yang, J.; Zhang, Y. “Nanostructured polypyrrole/carbon composite as Pt catalyst support for fuel cell applications” Journal of Power Sources 2008, 184, 375.
9 Luan, Y.; Zhang, Y.; Li, L.; Zhang, H.; Zhang, Q.; Huang, Z.; Liu, Y. “Perfluorosulfonic ionomer solution in N, N-dimethylformamide” Journal of Applied Polymer Science 2008, 107, 2892.
8 Zhao, H.; Li, L.; Yang, J.; Zhang, Y.; Li, H. “Synthesis and characterization of bimetallic Pt–Fe/polypyrrole–carbon catalyst as DMFC anode catalyst” Electrochemistry Communications 2008, 10, 876.
2007
7 Huang, Z.; Zhang, Y.; Li, H.; Liu, Y. “A novel immobilized cobalt (II)/copper (II) bimetallic catalyst for atom transfer radical polymerization (ATRP) of methyl methacrylate” Applied Catalysis A: General 2007, 332, 192.
6 Li, L.; Zhang, Y.; Drillet, J. F.; Dittmeyer, R.; Jüttner, K.M. “Preparation and characterization of Pt direct deposition on polypyrrole modified Nafion composite membranes for direct methanol fuel cell applications” Chemical Engineering Journal 2007, 133, 113.
2006
5 Li, H.; Zhang, Y. M.; Zhang, H.; Xue, M. Z.; Liu, Y. G. “Novel, well-defined polystyrene with a fluorine cluster end-capped group: Synthesis, characterization, and surface properties” Journal of Polymer Science Part A: Polymer Chemistry 2006, 44, 3853.
4 Huang, Z.; Zhang, Y.; Zhao, C.; Qin, J.; Li, H.; Xue, M.; Liu, Y. “Direct gas-phase epoxidation of hexafluoropropylene with molecular oxygen using Ag catalyst” Applied Catalysis A: General 2006, 303, 18.
2005
3 Dou, H. Y.; Ni, H.-B.; Zhao, C.-X.; Zhang, Y. M. “EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent” Journal of Fluorine Chemistry 2005, 126, 1130.
2 Li, Z. H.; Zhang, Y. M.; Xue, M. Z.; Zhou, L.; Liu, Y. G. “Atom transfer radical polymerization of methyl methacrylate catalyzed by cobalt catalyst system” Journal of Polymer Science Part A: Polymer Chemistry 2005, 43, 5207.
1 Li, Z.; Li, H.; Zhang, Y.; Xue, M.; Zhou, L.; Liu, Y. “A hybrid supported nickel catalyst for the controlled radical polymerization of methyl methacrylate” Applied Catalysis A: General 2005, 292, 61.
著作：
1 生物高分子第2卷類聚異戊二烯/[日] 古山種俊(Koyama, T.), [德] A. 斯泰陰比歇爾(Steinbüchel, A.) 主編; 劉燕剛，薛敏釗，張永明主譯. 北京：化學工業出版社(現代生物技術與醫藥科技出版中心) 2004, 8.
2 含氟功能材料. 張永明，李虹，張恒. 北京：化學工業出版社 2008.
3 PEM Fuel Cell Failure and Mode Analysis. Wang, H.; Li, H.; Yuan, X.-Z. Eds; Chapter 4, Luan, Y.; Zhang, Y. Membrane Degradation, Boca Raton: CRC Press, Taylor & Francis Group, 2011, December
Tel: 0086-21-34202613 Fax: 0086-21-54742567
E-mail : ymzhang@sjtu.edu.cn
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